Browsing by Author "López Poveda, Manuel"
Now showing items 1-20 of 20
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Article
A Diels–Alder Reaction Triggered by a [4 + 3] Metallacycloaddition
(American Chemical Society, 2015)The TpMe2Ir(III) complex 1-OH2 (TpMe2 = hydrotris(3,5-dimethylpyrazolyl)borate), which contains a labile molecule of water ...
- PhD Thesis
- PhD Thesis
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PhD Thesis
Complejos de Mo y W en estados de oxidación bajos. Compuestos de CO₂ y otros conteniendo ligandos derivados de CS₂
(1988-11)Este trabajo ha consistido en la síntesis y la caracterización, química y espectroscópica, de diversos complejos de MO y ...
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PhD Thesis
Contribución al estudio de carbenos N-heterocíclicos de Ir(III) derivados de piridinas
(2014-03-28)La investigación científica tiene como misión generar conocimiento que contribuya a solucionar las necesidades de la ...
- PhD Thesis
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Article
Coupling of Aromatic Aldehydes with CO2Me-Substituted TpMe2Ir(III) Metallacyclopentadienes
(American Chemical Society, 2012)The fully CO2Me substituted aquo-iridacyclopentadiene 1 reacts with a variety of aromatic aldehydes, at 90–120 °C, with ...
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Article
Electron-rich metal complexes for C02 and CS2 incorporation
(Walter de Gruyter GmbH, 1989)The dihapto coordination of two molecules of carbon dioxide to a square-planar MoP2(P-P) fragment (P=monodentate-, ...
- PhD Thesis
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Article
Facile Oxygen Atom Insertion into Unactivated C(sp3)-C(sp2) Single Bonds in Reactions of Iridium(III) Complexes with O2
(American Chemical Society, 2013)The Ir(III) pyridylidene TpMe2tiebar above startr(CH2CH2-o-tiebar above endC6H4)(tiebar above startCN(H)CHCHCHtiebar above ...
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Article
Formation of β-Metallanaphthalenes by the Coupling of a Benzo-Iridacyclopentadiene with Olefins
(American Chemical Society, 2015)We have synthesized a new type of metallaaromatic complexes, namely the hydride-β-iridanaphthalenes TpMe2tiebar above ...
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Article
Functionalization of 3-Iridacyclopentenes
(Wiley, 2017)Members of a series of iridacyclopentenes of composition [TpMe2Ir(k2-C,C-CH2CR′=CRCH2)(CO)] (TpMe2=hydrotris(3,5-dimethylpyrazolyl)borate; ...
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Article
Investigations on the Coupling of Ethylene and Alkynes in Tp Me2 Ir Compounds: Water as an Effective Trapping Agent
(Wiley-VCH, 2007)The reaction of the bis(ethylene) complex [TpMe2Ir(C2H4)2] (1) (TpMe: hydrotris(3,5-dimethylpyrazolyl)borate) with two ...
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PhD Thesis
Late transition metal organometallic chemistry. rhodium, iridium and gold complexes with sigma and pi hydrocarbon-based ligands.
(2015-10-29)Los resultados que se presentan en esta Memoria se encuadran en una de las líneas de investigación que desarrolla el grupo ...
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PhD Thesis
Pirrolil, hidroxo y carbonato complejos organometálicos de niquel. Inserción de isonitrilos enlos enlaces niquel-carbono
(1986-10-01)La tesis doctoral ha tenido por objeto la síntesis y la caracterización química y espectroscópica de alquil y aril derivados ...
- PhD Thesis
- PhD Thesis
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Article
Reactivity of TpMe2-containing hydride-iridafurans with alkenes, alkynes, and H2
(American Chemical Society, 2014)The TpMe2-containing hydride-iridafurans 2a,b (TpMe2 = hydrotris(3,5-dimethylpyrazolyl)borate) cleanly reacted with ethylene ...
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Article
Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2, 2 ':6 ', 2''-terpyridine
(Royal Society of Chemistry, 2009)Thermal activation of terpyridine in the presence of an unsaturated Ir(III) fragment stabilized by a hydrotris(pyrazolyl) borate ...
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PhD Thesis
Tautomeria de heterociclos nitrogenados mediante complejos de iridio (III) con formación de carbenos n-heterocíclicos
(2010-06-24)En el presente trabajo se han llevado a cabo diversos estudios fundamentales sobre procesos básicos en Química Organometálica. ...