Browsing by Author "Gonzalo Calvo, Gonzalo de"
Asymmetric organocatalytic synthesis of tertiary azomethyl alcohols: key intermediates towards azoxy compounds and α-hydroxy-β-amino esters [Article]Carmona, José A.; Gonzalo Calvo, Gonzalo de; Serrano Vallez, Inmaculada; Crespo-Peña, Ana; Šimek, Michal; Monge Fernández, David; Fernández, Rafael; Lassaletta, José M. (Royal Society of Chemistry (Great Britain), 2017)
A series of peracylated glycosamine-derived thioureas have been synthesized and their behavior as bifunctional organocatalysts has been tested in the enantioselective nucleophilic addition of formaldehyde tert-butyl hydrazone ...
Biocatalysis as Useful Tool in Asymmetric Synthesis: An Assessment of Recently Granted Patents (2014–2019) [Article]Domínguez de María, Pablo; Gonzalo Calvo, Gonzalo de; Alcántara, Andrés R. (MDPI, 2019-09-25)
The broad interdisciplinary nature of biocatalysis fosters innovation, as different technical fields are interconnected and synergized. A way to depict that innovation is by conducting a survey on patent activities. This ...
Correction: de Gonzalo, G. Lipase Catalysed Kinetic Resolution of Racemic 1,2-Diols Containing a Chiral Quaternary Center. Molecules 2018, 23, 1585 [Article]Gonzalo Calvo, Gonzalo de (MDPI, 2018)
Lipase catalysed kinetic resolution of racemic 1,2-diols containing a chiral quaternary center [Article]Gonzalo Calvo, Gonzalo de (MDPI, 2018)
Optically active 1,2-diols are valuable buildings blocks in organic synthesis. In the present paper, a set of racemic 1,2-diols with an ester functional group are prepared, starting from -ketoesters in a three-step ...
Willot, Sébastien Jean-Paul; Tieves, Florian; Girhard, Marco; Urlacher, Vlada B.; Hollmann, Frank; Gonzalo Calvo, Gonzalo de (MDPI, 2019)
A set of dual functional small molecules (DFSMs) containing different amino acids has been synthesized and employed together with three different variants of the cytochrome P450 monooxygenase P450BM3 from Bacillus ...
Polycyclic Ketone Monooxygenase (PockeMO): A Robust Biocatalyst for the Synthesis of Optically Active Sulfoxides [Article]Gonzalo Calvo, Gonzalo de; Fürst, Maximilian J. L. J.; Fraaije, Marco W. (Multidisciplinary Digital Publishing Institute (MDPI), 2017)
recently discovered, moderately thermostable Baeyer-Villiger monooxygenase, polycyclic ketone monooxygenase (PockeMO), from Thermothelomyces thermophila has been employed as a biocatalyst in a set of asymmetric sulfoxidations. ...
Stereoselective enzymatic reduction of 1,4-diaryl-1,4-diones to the corresponding diols employing alcohol dehydrogenases [Article]Mourelle Insua, Ángela; Gonzalo Calvo, Gonzalo de; Lavandera, Iván; Gotor Fernández, Vicente (MDPI, 2018)
Due to the steric hindrance of the starting prochiral ketones, the preparation of chiral 1,4-diaryl-1,4-diols through the asymmetric hydrogen transfer reaction has been mainly restricted to the use of metal-based catalysts, ...