Browsing by Author "Campos Manzano, Jesús"
Now showing items 1-19 of 19
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Article
A highly constrained cis-dihydride platinum complex trapped by cooperative gold/platinum dihydrogen activation
(Royal Society of Chemistry, 2022)A series of Au(I)/Pt(0) combinations that behave as bimetallic frustrated Lewis pairs activates dihydrogen in a cooperative ...
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Article
A versatile approach to access trimetallic complexes based on trisphosphinite ligands
(Multidisciplinary Digital Publishing Institute (MDPI), 2020)A straightforward method for the preparation of trisphosphinite ligands in one step, using only commercially available ...
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Article
Base-Promoted, Remote C−H Activation at a Cationic (η5 ‑C5Me5)Ir(III) Center Involving Reversible C−C Bond Formation of Bound C5Me5
(American Chemical Society, 2019)C-H bond activation at cationic [(η5-C5Me5)Ir(PMe2Ar')] centers is described, where PMe2Ar' are the terphenyl phosphine ...
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Article
Cationic (η5-C5Me4R)RhIII Complexes with Metalated Aryl Phosphines Featuring η4-Phosphorus plus Pseudo-Allylic Coordination
(American Chemical Society, 2018)In this contribution we study experimentally and computationally some electrophilic cationic (η5-C5Me4R)RhIII complexes ...
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Patent
Complejos cationicos con ligandos ciclopentadienilo y su uso como catalizadores para la preparacion de silanos deuterados y tritiados
(Oficina Española de Patentes y Marcas , 2011-12-13)La presente invención se refiere a diversos complejos catiónicos de los metales cobalto, rodio e iridio conteniendo ligandos ...
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PhD Thesis
Complejos de oro (I) con fosfinas voluminosas y diseño de estructuras organometálicas polinucleares
(2022-01-14)El inicio de la Química Organometálica moderna data de 1952 con la elucidación de la estructura tipo sándwich del ferroceno ...
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PhD Thesis
Cooperative Bond Activation by Bimetallic Frustrated Lewis Pairs and Related Systems
(2021-09-10)La química organometálica, química de las moléculas con enlaces metal-carbono (y normalmente extendida también a aquellas ...
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Article
Coordination of LiH Molecules to Mo≣Mo Bonds: Experimental and Computational Studies on Mo2LiH2, Mo2Li2H4, and Mo6Li9H18 Clusters
(American Chemical Society, 2021)The reactions of LiAlH4 as the source of LiH with complexes that contain (H)Mo≣Mo and (H)Mo≣Mo(H) cores stabilized by the ...
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Article
Evaluating stereoelectronic properties of bulky dialkylterphenyl phosphine ligands
(Elsevier, 2019)The stereoelectronic properties of a series of sterically hindered phosphines containing a terphenyl substituent, PR2Ar’ ...
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Article
Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with Gold(I)/Platinum(0) Systems
(Wiley-Blackwell, 2020)A joint experimental/computational effort to elucidate the mechanism of dihydrogen activation by a gold(I)/platinum(0) ...
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Article
Large-scale preparation and labelling reactions of deuterated silanes
(John Wiley & Sons, 2012)A catalytic synthesis of deuterated silanes SiEt3D, SiMe2PhD and SiPh2D2 is reported that allows their facile generation ...
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Article
Reactivity of a trans-[H-Mo≣Mo-H] Unit Towards Alkenes and Alkynes. Bimetallic Migratory Insertion, H-Elimination and Other Reactions
(Royal Society of Chemistry, 2018)Complex [Mo2(H)2{μ-HC(NDipp)2}2(THF)2], (1·THF), reacts with C2H4 and PhCH[double bond, length as m-dash]CH2 to afford ...
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Article
Reactivity of a gold(i)/platinum(0) frustrated Lewis pair with germanium and tin dihalides
(Royal Society of Chemistry, 2019)The reactivity of germanium and tin dichlorides with a transition metal-only frustrated Lewis pair based on Au(i) and Pt(0) ...
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PhD Thesis
Reactivity of Quadruply Bonded Dimolybdenum Hydride Centres: Elementary Organometallic Reactions and Coordination to Main-Group Metal‒Carbon and Metal‒Hydrogen Bonds
(2021-07-08)En esta Tesis se investigan complejos bimetálicos de molibdeno estabilizados por ligandos amidinato bidentados voluminosos ...
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Article
Reductive C–C Coupling from Molecular Au(I) Hydrocarbyl Complexes: A Mechanistic Study
(American Chemical Society, 2021)Organometallic gold complexes are used in a range of catalytic reactions, and they often serve as catalyst precursors that ...
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Article
Synthesis and reactivity of half-sandwich (η 5 -C 5 Me 5 )Ir(iii) complexes of a cyclometallated aryl phosphine ligand
(Royal Society of Chemistry, 2011)Reaction of the Ir(iii) dimer [(η 5 -C 5 Me 5 )IrCl 2 ] 2 with PMeXyl 2 (Xyl = 2,6-C 6 H 3 Me 2 ), in the presence of the ...
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PhD Thesis
Synthesis, Characterization and Cooperative Reactivity of Polarized Bimetallic Systems
(2023-01-13)Los resultados presentados en esta Tesis se enmarcan en una de las líneas de investigación desarrolladas por el Grupo de ...
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Article
Synthesis, properties, and some rhodium, iridium, and platinum complexes of a series of bulky m-terphenylphosphine ligands
(Elsevier, 2016)A series of sterically demanding aryl phosphine ligands (L) bearing terphenyl substituents, PR2Ar′ (R = hydrocarbyl, Ar′ ...
- PhD Thesis