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Browsing by Author "Álvarez, Santiago"
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Article
An Unsaturated Four-Coordinate Dimethyl Dimolybdenum Complex with a Molybdenum–Molybdenum Quadruple Bond
Curado, Natalia; Carrasco, Mario; Campos, Jesús; Maya Díaz, Celia María; Rodríguez, Amor; Ruiz, E.; Álvarez, Santiago; Carmona Guzmán, Ernesto (John Wiley & Sons, 2017)We describe the synthesis and the molecular and electronic structures of the complex [Mo2Me2{μ‐HC(NDipp)2}2] (2; ...
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Article
Coordination of LiH Molecules to Mo≣Mo Bonds: Experimental and Computational Studies on Mo2LiH2, Mo2Li2H4, and Mo6Li9H18 Clusters
Pérez Jiménez, Marina; Curado, Natalia; Maya Díaz, Celia María; Campos Manzano, Jesús; Jover, Jesús; Álvarez, Santiago; Carmona Durán, Ernesto (American Chemical Society, 2021)The reactions of LiAlH4 as the source of LiH with complexes that contain (H)Mo≣Mo and (H)Mo≣Mo(H) cores stabilized by the ...
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Article
Electronic and structural effects of low-hapticity coordination of arene rings to transition metals
Falceto, Andrés; Carmona Guzmán, Ernesto; Álvarez, Santiago (American Chemical Society, 2014)A DFT computational study and a structural analysis of the coordination of arenes to transition metals in low -hapticity ...
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Article
Experimental and Computational Studies of the Molybdenum-Flanking Arene Interaction in Quadruply Bonded Dimolybdenum Complexes with Terphenyl Ligands
Carrasco, Mario; Mendoza, Irene; Álvarez González, Eleuterio; Grirrane, Abdessamad; Maya Díaz, Celia María; Peloso, Riccardo; Rodríguez, Amor; Falceto, Andrés; Álvarez, Santiago; Carmona Durán, Ernesto (Wiley, 2015)To clarify the nature of the Mo[BOND]Carene interaction in terphenyl complexes with quadruple Mo[BOND]Mo bonds, ether ...
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Article
Supported σ-Complexes of Li−C Bonds from Coordination of Monomeric Molecules of LiCH3, LiCH2CH3 and LiC6H5 to Mo≣Mo Bonds
Pérez Jiménez, Marina; Campos, Jesús; Jover, Jesús; Álvarez, Santiago; Carmona Guzmán, Ernesto (German Chemical Society, 2022)LiCH3 and LiCH2CH3 react with the complex [Mo2(H)2(μ-AdDipp2)2(thf)2] (1⋅thf) with coordination of two molecules of LiCH2R ...