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Listar por autor "Rosales Martínez, Antonio"
Mostrando ítems 1-16 de 16
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Artículo
A Concise Diastereoselective Total Synthesis of α-Ambrinol
López-Martínez, Josefa L.; Torres-García, Irene; Moreno-Gutiérrez, Irene; Oña Burgos, Pascual; Rosales Martínez, Antonio; Muñoz-Dorado, Manuel; Álvarez-Corral, Míriam; Rodríguez-García, Ignacio (MDPI, 2023-03)(−)-cis-α-Ambrinol is a natural product present in ambergris, a substance of marine origin that has been highly valued by ...
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Artículo
A Concise Route for the Synthesis of Tetracyclic Meroterpenoids: (±)-Aureol Preparation and Mechanistic Interpretation
Rosales Martínez, Antonio; Enríquez Giraudo, Lourdes; Jaraíz Maldonado, Martín; Pozo-Morales, Laura; Rodríguez-García, Ignacio; Díaz Ojeda, Emilio (MDPI, 2020-08)A new concise general methodology for the synthesis of different tetracyclic meroterpenoids is reported: (±)-aureol (1), ...
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Artículo
Cp2TiCl/D2O/Mn, a formidable reagent for the deuteration of organic compounds
Rosales Martínez, Antonio; Rodríguez-García, Ignacio (Beilstein-Institut, 2016)Cp2TiCl/D2O/Mn is an efficient combination, sustainable and cheap reagent that mediates the D-atom transfer from D2O to ...
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Artículo
Cp₂TiCl is a useful reagent to teach multidisciplinary chemistry
Rosales Martínez, Antonio (Universidad Nacional Autónoma de México (UNAM), 2021-10-04)Cp₂TiCl es un único reactivo de transferencia de electrones que ha contribuido en varios campos del conocimiento científico, ...
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Artículo
Cp₂TiCl/H₂O as a Sustainable System for the Reduction of Organic Functional Groups: Potential Application of Cp2TiCl/D2O to the Analysis of Bioactive Phenols in Olive Oil
Rosales Martínez, Antonio; García-Martín, Juan Francisco; Rodríguez-García, Ignacio (MDPI, 2023-03)Significant efforts have been made toward developing sustainable reduction reactions of organic and bioorganic compounds. ...
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Ponencia
Cp₂TiCl/Mn/D₂O: un reactivo verde para la deuteración de moléculas orgánicas
Rosales Martínez, Antonio; Rodríguez, I.; Pozo-Morales, Laura; Roldán, E.; Rodríguez, R.; Moncayo, P. (Área de Innovación y Desarrollo, 2016)En esta revisión se recoge una descripción detallada de la deuteración de moléculas orgánicas utilizando la mezcla ...
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Artículo
Divergent Strategy in Marine Tetracyclic Meroterpenoids Synthesis
Rosales Martínez, Antonio; Rodríguez-García, Ignacio; López-Martínez, Josefa L. (MDPI, 2021-05)The divergent total synthesis strategy can be successfully applied to the preparation of families of natural products using ...
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Artículo
Green reductive regioselective opening of epoxides. A green chemistry laboratory experiment
Rosales Martínez, Antonio; Rodríguez-García, Ignacio; López-Martínez, Josefa L. (American Chemical Society, 2022-06)Green chemistry is finding its place as one of the most essential study topics in the curriculum of future chemists and ...
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Artículo
Hydrogen/Deuterium Exchange in Ambrox Could Improve the Long-Term Scent and Shelf Life of Perfumes
Rosales Martínez, Antonio; Rodríguez-García, Ignacio (MDPI, 2023-08)Ambrox is a marine natural compound with a delicious ambergris-type scent widely used in fine perfumery. The increase in ...
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Artículo
Marine Puupehenone and Puupehedione. Synthesis and Future Perspectives
Rosales Martínez, Antonio; Rodríguez-García, Ignacio (MDPI, 2023-05)Puupehenone and puupehedione are natural products isolated from marine organisms. These compounds display a broad spectrum ...
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Trabajo Fin de Grado
Optimización energética de una refinería de aceite vegetal en la provincia de Sevilla
Díaz Haro, Francisco José (2022)En el presen te apartado vamos a acompañar al lector en una vista somera y superficial sobre el trabajo que nos lleva, ...
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Artículo
Photochemical water splitting via transition metal complexes
Rosales Martínez, Antonio; Rodríguez-García, Ignacio (Elsevier, 2024-04)Photochemical water splitting by transition metal complexes provides a new approach to the production of hydrogen as a ...
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Artículo
The deuteration of organic compounds as a tool to teach chemistry
Rosales Martínez, Antonio (Publicaciones y Fomento Editorial de la UNAM, 2022-09)The deuteration of organic compounds has contributed to several fields of scientific knowledge, such as analytical, ...
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Trabajo Fin de Grado
Titanocene monochloride (Cp2TiCl): a formidable tool in 2 contemporary radical and organometallic chemistry
García Ocaña, Marta (2016)The vast range of reactions mediated by titanocene monochloride (Cp2TiCl) in organic synthetic chemistry is reviewed. The ...
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Artículo
Understanding the color change of the solutions of Cp₂TiCl upon addition of water
Rosales Martínez, Antonio; Enríquez Giraudo, Lourdes; Jaraíz Maldonado, Martín; Thiessen, Tanner; Sidhu, Jaspreet; McIndoe, J. Scott; Rodríguez-García, Ignacio (Wiley, 2023-02)Reduction of red bis (cyclopentadienyl)titanium (IV) dichloride (Cp₂TiCl₂) with manganese dust in dry THF produces a green ...
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Artículo
Unifying the Synthesis of a Whole Family of Marine Meroterpenoids through a Biosynthetically Inspired Sequence of 1,2-Hydride and Methyl Shifts as Key Step
Rosales Martínez, Antonio; Rodríguez-Maecker, Román Nicolay; Rodríguez-García, Ignacio (MDPI, 2023-02)Marine meroterpenoids have attracted a great deal of attention from synthetic research groups due to their attractive and ...