dc.creator | Sánchez Mellado, Práxedes | es |
dc.creator | Hernández Juárez, Martín | es |
dc.creator | Rendón Márquez, Nuria | es |
dc.creator | López Serrano, Joaquín | es |
dc.creator | Álvarez González, Eleuterio | es |
dc.creator | Paneque Sosa, Margarita | es |
dc.creator | Suárez Escobar, Andrés Luis | es |
dc.date.accessioned | 2022-10-26T11:13:09Z | |
dc.date.available | 2022-10-26T11:13:09Z | |
dc.date.issued | 2018 | |
dc.identifier.citation | Sánchez Mellado, P., Hernández Juárez, M., Rendón Márquez, N., López Serrano, J., Álvarez González, E., Paneque Sosa, M. y Suárez Escobar, A.L. (2018). Hydroboration of carbon dioxide with catechol- and pinacolborane using an Ir–CNP* pincer complex. Water influence on the catalytic activity. Dalton, 47, 16766-16776. https://doi.org/10.1039/C8DT03951H. | |
dc.identifier.issn | 1477-9226 | es |
dc.identifier.issn | 1477-9234 | es |
dc.identifier.uri | https://hdl.handle.net/11441/138366 | |
dc.description.abstract | Iridium complexes based on deprotonated lutidine-derived CNP* pincers 2a/2b selectively catalyzed the
hydroboration of CO2 under mild conditions (1–2 bar CO2, 30 °C) to methoxyborane using HBcat (TOF
up to 56 h−1
) and to the formate level with HBpin (TOF up to 1245 h−1
). Interestingly, an intriguing, positive
water effect on the reaction rates has been observed. NMR spectroscopy and ESI-MS analysis of the
hydroboration reactions have shown the formation of ligand-protonated [Ir(CNP)(CO)(BR2)H][B(R2)2] (R2 =
catecholate, pinacolate) derivatives under catalytic conditions. Control experiments, however, have
demonstrated that these derivatives are not catalytically competent species in the hydroboration of CO2. | es |
dc.description.sponsorship | Ministerio de Economía y Competitividad de España (MINECO) y fondos FEDER de la Unión Europea-CTQ2016-80814-R y CTQ2016-81797-REDC | es |
dc.format | application/pdf | es |
dc.format.extent | 11 p. | es |
dc.language.iso | eng | es |
dc.publisher | Royal Society of Chemistry | es |
dc.relation.ispartof | Dalton, 47, 16766-16776. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Hydroboration of carbon dioxide with catechol- and pinacolborane using an Ir–CNP* pincer complex. Water influence on the catalytic activity | es |
dc.type | info:eu-repo/semantics/article | es |
dc.type.version | info:eu-repo/semantics/acceptedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | CTQ2016-80814-R | es |
dc.relation.projectID | CTQ2016-81797-REDC | es |
dc.relation.publisherversion | https://doi.org/10.1039/C8DT03951H | es |
dc.identifier.doi | 10.1039/C8DT03951H | es |
dc.journaltitle | Dalton | es |
dc.publication.volumen | 47 | es |
dc.publication.initialPage | 16766 | es |
dc.publication.endPage | 16776 | es |
dc.contributor.funder | Ministerio de Economía y Competitividad (MINECO). España | es |
dc.contributor.funder | European Commission (EC). Fondo Europeo de Desarrollo Regional (FEDER) | es |