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Mostrando ítems 1-10 de 12
Artículo
WGS and CO-PrOx reactions using gold promoted copper-ceria catalysts: “bulk CuO-CeO2 vs. CuO-CeO2/Al2O3 with low mixed oxide content”
(Elsevier, 2016)
A copper-ceria bulk catalyst has been compared to a series of catalysts designed according to the as called “supported approach”, corresponding to the dispersion of low content mixed copper-ceria oxide on alumina matrix. ...
Artículo
Could an efficient WGS catalyst be useful in the CO-PrOx reaction?
(Elsevier, 2014)
This work presents an evaluation of a high performance series of water gas shift (WGS) catalysts in the preferential CO oxidation reaction (PrOx) in order to examine the applicability of the same catalyst for both processes ...
Artículo
Sub-ambient CO oxidation over Au/MO x/CeO 2-Al 2O 3 (M = Zn or Fe)
(Elsevier, 2012)
A series of ZnO and Fe 2O 3 modified ceria/alumina supports and their corresponding gold catalyst were prepared and studied in the CO oxidation reaction. ZnO-doped solids show a superior catalytic activity compared to the ...
Artículo
O2-assisted Water Gas Shift reaction over structured Au and Pt catalysts
(Elsevier, 2016)
Platinum and gold structured catalysts were compared as active phases in classical and O2-assisted Water Gas Shift (WGS) reaction. Both metals were supported on iron-doped ceria mixed oxide and then, structured on metallic ...
Artículo
The role of Au, Cu & CeO2 and their interactions for an enhanced WGS performance
(Elsevier, 2016)
The WGS reaction over multicomponent Au/Ce1-xCuxO2/Al2O3 catalysts is studied in this work. The systems are carefully designed aiming to take advantage of every active phase included in the formulation: gold, ceria and ...
Artículo
Bimetallic Ni–Ru and Ni–Re Catalysts for Dry Reforming of Methane: Understanding the Synergies of the Selected Promoters
(Frontiers Media, 2021)
Designing an economically viable catalyst that maintains high catalytic activity and stability is the key to unlock dry reforming of methane (DRM) as a primary strategy for biogas valorization. Ni/Al2O3 catalysts have ...
Artículo
Boosting the activity of a Au/CeO2/Al2O3 catalyst for the WGS reaction
(Elsevier, 2015)
Herein a strategy to design highly efficient Au/CeO2/Al2O3 based WGS catalysts is proposed. The inclusion of transition metals, namely Fe, Cu and Zn as CeO2 dopant is considered. All the promoters successfully increased ...
Artículo
Chemical CO2 recycling via dry and bi reforming of methane using Ni-Sn/ Al2O3 and Ni-Sn/CeO2-Al2O3 catalysts
(Elsevier, 2018)
Carbon formation and sintering remain the main culprits regarding catalyst deactivation in the dry and bireforming of methane reactions (DRM and BRM, respectively). Nickel based catalysts (10 wt.%) supported on alumina ...
Artículo
H2 oxidation as criterion for PrOx catalyst selection: Examples based on Au-CoOx-supported systems
(Elsevier, 2015-06-01)
A new approach for understanding PrOx reaction over gold catalysts is proposed in this work. The competition between H2 and CO oxidation has been studied over a series of Au/MOx/Al2O3 (M = Ce and Co) catalysts in simulated ...
Artículo
Pt vs. Au in water-gas shift reaction
(Elsevier, 2014)
This work presents a comparison of the gold- and platinum-based catalysts behavior in the water-gas shift (WGS) reaction. The influence of the support, e.g., its composition and electronic properties, studied in detail by ...